噴施稀土對(duì)茶葉中不同狀態(tài)的稀土元素組成及含量的影響
用蒸餾水為玻璃雙蒸水,所用化學(xué)試劑為上海試劑二廠產(chǎn)品,分析純。 2 結(jié)果與討論 2.1 噴施稀土對(duì)tea .com/'>茶葉中REE組成及含量的影響
不同施稀土的tea .com/'>茶葉中REE的組成也同土壤一樣,以La、Ce和Nd為主,但La含量在組成中所占比例與土壤中相比顯著上升,而Ce則相反(表2、表3)。這說明tea .com/'>茶樹對(duì)土壤中稀土有選擇性吸收,對(duì)La等吸收較多;與此同時(shí)對(duì)一些重稀土如Tm、Yb、Ho等,tea .com/'>茶樹則吸收較少。這與陳照喜等〔10〕提出的tea .com/'>茶樹對(duì)ΣCe有較強(qiáng)的富集作用觀點(diǎn)相一致。表3 噴施稀土對(duì)tea .com/'>茶葉中REE組成及含量(μg/g)的影響Table 3 Effects of spraying RE on compositionpercentage and component content (μg/g)of REE in tea samples from RE treatment on various days 元素對(duì)照 3月11日噴施 3月22日噴施 4月1日噴施 Y 0.135±0.012 0.141±0.002 0.117±0.002 0.121±0.002 (6.55) (6.17) (5.02) (4.18) La 0.742±0.012 0.863±0.020 1.003±0.010 1.302±0.005 (36.00) (37.71) (43.07) (44.94) Ce 0.598±0.014 0.644±0.003 0.562±0.002 0.670±0.015 (28.58) (28.18) (24.13) (23.13) Pr 0.104±0.001 0.114±0.002 0.117±0.003 0.154±0.003 (5.05) (4.99) (5.02) (5.32) Nd 0.311±0.001 0.361±0.007 0.370±0.016 0.472±0.032 (15.09) (15.80) (15.87) (16.29) Sm 0.043±0.002 0.048±0.001 0.043±0.002 0.051±0.002 (2.09) (2.10) (1.85) (1.76) Eu 0.009±0.001 0.011±0.001 0.009±0.001 0.011±0.000 (0.44) (0.48) (0.39) (0.38) Gd 0.049±0.002 0.047±0.001 0.049±0.001 0.054±0.000 (2.38) (2.06) (2.10) (1.86) Tb 0.005±0.001 0.006±0.000 0.005±0.000 0.006±0.000 (0.24) (0.26) (0.21) (0.21) Dy 0.022±0.002 0.026±0.003 0.022±0.000 0.022±0.002 (1.07) (1.14) (0.94) (0.76) Ho 0.005±0.000 0.005±0.000 0.005±0.000 0.005±0.000 (0.24) (0.22) (0.21) (0.17) Er 0.012±0.001 0.015±0.001 0.012±0.000 0.014±0.002 (0.58) (0.66) (0.52) (0.48) Tm 0.002±0.000 0.002±0.000 0.002±0.000 0.002±0.000 (0.10) (0.09) (0.09) (0.07) Yb 0.011±0.001 0.013±0.001 0.011±0.000 0.011±0.001 (0.53) (0.57) (0.47) (0.38) Lu 0.002±0.001 0.002±0.000 0.002±0.000 0.002±0.000 (0.10) (0.09) (0.09) (0.07) ΣCe 1.798 2.041 2.104 2.660 (87.24) (89.32) (90.34) (91.82) ΣY 0.263 0.244 0.255 0.237 (12.76) (10.68) (9.66) (8.18) ΣCe/ΣY 6.836 8.356 9.351 11.223 ΣREE 2.061 2.285 2.329 2.897
注:ΣCe=La~Eu的含量總和,即鈰組或輕稀土總量;ΣY=Gd~Lu和Y的含量總和,即釔組或重稀土總量;ΣREE為15種稀土元素(除Pm、Sc外)的含量總和(表4~5同)
噴施稀土對(duì)成品tea .com/'>茶中稀土總量的影響表現(xiàn)在:ΣREE隨噴施與tea .com/look.php?sid=4198'>采摘 的間隔期延長(zhǎng)而減少(表3)。間隔期為15天(4月1日噴施的)時(shí),成品tea .com/'>茶中稀土總量比對(duì)照高約43%